大学物理 ›› 2021, Vol. 40 ›› Issue (4): 27-31.doi: 10. 16854 / j. cnki. 1000-0712. 200314

• 物理实验 • 上一篇    下一篇

结合有效介质理论的乳状液太赫兹光谱分析

李 超,秦凡凯,孟昭晖,陈 儒,杨 颀,杨义勤,苗昕扬,赵 昆,詹洪磊   

  1. 中国石油大学( 北京) 新能源与材料学院 石油和化工行业油气太赫兹波谱与光电检测重点实验室,北京 102249
  • 收稿日期:2020-07-17 修回日期:2020-08-31 出版日期:2021-04-13 发布日期:2021-04-21
  • 通讯作者: 詹洪磊,E-mail: zhanhl@ cup. edu. cn
  • 作者简介:李 超( 1995—) ,男,山东济南人,中国石油大学( 北京) 2019 级研究生.
  • 基金资助:
    中国石油大学( 北京) 研究生教育质量与创新工程重点项目( 以培养行业交叉卓越人才为目标的《油气光学》研究生精品示范课程建设,yjs2019005) ; 国家自然科学基金(11804392)

Terahertz spectral analysis of emulsion combined with effective medium theory

LI Chao,QIN Fan-kai,MENG Zhao-hui,CHEN Ru,YANG Qi, YANG Yi-qin,MIAO Xin-yang,ZHAO Kun,ZHAN Hong-lei   

  1. College of New Energy and Materials,Key Laboratory of Oil and Gas Terahertz Spectroscopy and Photoelectric Detection in Petroleum and Chemical Industry,China University of Petroleum,Beijing 102249,China
  • Received:2020-07-17 Revised:2020-08-31 Online:2021-04-13 Published:2021-04-21

摘要: 原油乳状液对原油的长距离输运具有重要影响,乳状液的油、水状态及相互作用机制还需新理论和新方法获得新认识,基于有效介质理论,本文研究了原油乳状液太赫兹光谱响应特征. 通过太赫兹时域光谱系统测试得到了含水率为 0 ~ 28 % 的原油乳状液的太赫兹时域光谱,结合傅里叶变换计算了吸收系数和介电常数等光学参数,同一频率下吸收系数等光学参数随含水率增加而增大. 样品的实际介电常数与 Bruggeman 理论计算的介电常数一致,最大误差率低于 3 % ,说明含水率较小时,水分散在原油中,微粒间的距离较大,微粒间的相互作用力较小,随着含水率增加,水相和油相混合分布,微粒间的距离会变小,微粒的相互作用力会变大. 因此,有效介质理论对乳状液的太赫兹光谱研究具有重要意义.

关键词: 原油乳状液, 太赫兹, 有效介质理论, 介电常数

Abstract: Crude oil emulsions have an important influence on the long-distance transportation of crude oil. The oil and water state of the emulsion and the interaction mechanism require new theories and new methods. The terahertz spectrum ( THz- TDS) response of

crude oil emulsion is studied based on the effective medium theory. The THz-TDS of emulsions with water content of 0 ~ 28 % are obtained by using the THz-TDS system. The optical parameters such as absorption coefficient and dielectric constant are calculated by

Fourier transform. The optical parameters increase with the increase of water content of emulsions. The actual dielectric constant is consistent with the dielectric constant calculated by Bruggeman's theory,and the maximum error rate is less than 3 % . The results show that when the

water content is small,the water is dispersed in the crude oil,the distance between the particles is large,and the interaction force between the particles is small. As the water content increases,the water phase and the oil phase are mixed and distributed,the distance between the

particles will become smaller,and the inter- action force of the particles will become larger.Therefore,the effective medium theory is significant to investigate the THz spectrum of oil-water emulsions.

Key words: crude oil emulsion, terahertz, effective medium theory, dielectric constant