教学讨论

热容量表述与能斯特表述等效的严格证明

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  • 厦门大学 物理学系,福建 厦门361005
周颖慧(1982—),女,福建泉州人,厦门大学物理学系教授,博士,从事热力学统计物理相关的教学科研工作.
陈金灿,E-mail: jcchen@xmu.edu.cn

收稿日期: 2025-06-04

  修回日期: 2025-09-05

  网络出版日期: 2026-06-04

基金资助

福建省高校物理学学科联盟教育教学改革研究项目(FJPHYS-2023)资助

Strict proof on the equivalence of the heat capacity statement and the #br# Nernst statement#br#

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  • Department of Physics, Xiamen University, Xiamen, Fujian 361005, China

Received date: 2025-06-04

  Revised date: 2025-09-05

  Online published: 2026-06-04

摘要

本文采用几种不同的方法严格地证明热容量表述与能斯特表述是可相互推导的、是等效的. 应用这两种表述取代一百多年来出现在教科书中的能斯特定理和/或绝对零度不能达到原理,成为热力学第三定律的创新表述,可确保热力学第三定律是客观世界的真实反映,从而完善经典热力学理论体系.

本文引用格式

周颖慧, 苏山河, 赵英汝, 陈金灿 . 热容量表述与能斯特表述等效的严格证明[J]. 大学物理, 2026 , 45(3) : 35 . DOI: 10.16854/j.cnki.1000-0712.250301

Abstract

Several different methods are used to prove strictly that the heat capacity statement and the Nernst statement are mutually derivable and equivalent. The application of the two statements to replace the Nernst theorem and/or the unattainability principle of absolute zero temperature, which have appeared in textbooks for more than one hundred years, as the innovative statements of the third law of thermodynamics can ensure that the third law of thermodynamics is a true reflection of the objective world, thus improving the theoretical system of classical thermodynamics. 


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