大学物理 ›› 2025, Vol. 44 ›› Issue (10): 11-.doi: 10.16854/j.cnki.1000-0712.240571

• 教学研究 • 上一篇    下一篇

无需附加假设的能斯特公式及其诠释

王远,周颖慧,陈金灿   

  1. 1. 河南工程学院理学院,河南 郑州451191;2. 厦门大学物理系,福建 厦门361005
  • 收稿日期:2024-12-06 修回日期:2025-03-11 出版日期:2025-12-20 发布日期:2025-12-27
  • 作者简介:王远(1968—),男,江苏徐州人,河南工程学院副教授,博士,主要从事热力学统计物理的教学研究工作.
  • 基金资助:
    河南省本科高校青年骨干教师培养计划(2023GGJS159);福建省高校物理学学科联盟教育教学改革研究项目(FJPHYS2023A02)资助

The Nernst equation without additional assumptions and its interpretation

WANG Yuan1,2, ZHOU Ying-hui2,CHEN Jin-can2   

  1. 1. College of Science, Henan University of Engineering, Zhengzhou 451191;2. Department of Physics, Xiamen University, Xiamen 361005
  • Received:2024-12-06 Revised:2025-03-11 Online:2025-12-20 Published:2025-12-27

摘要: 本文引入一个新的热力学函数,利用低温热力学系统在等温等压过程中焓和吉布斯函数的改变量的实验数据模拟出该函数随温度的变化曲线,将实验模拟结果外推到绝对零度时,无需引入附加假设直接获得能斯特公式. 指出无附加假设的能斯特公式应被称为能斯特表述而不是能斯特定理,可作为热力学第三定律表述的核心内容. 进而对能斯特公式的物理内涵作出更为准确的诠释.

关键词: 能斯特公式, 能斯特定理, 能斯特表述, 热力学第三定律

Abstract: A new thermodynamic function is introduced and the curve of the function varying with temperature is simulated by using the experimental data of the enthalpy and Gibbs function changes during the isothermal and isobaric process of low temperature thermodynamic systems. The Nernst equation is obtained directly by extrapolating the experimental simulation results to absolute zero without introducing additional assumptions. It is pointed out that the Nernst equation without additional assumptions should be called the Nernst statement instead of the Nernst theorem, and can be the core content of the statement of the third law of thermodynamics. Moreover, the physical connotations of the Nernst equation are explained more accurately.

Key words: Nernst equation, Nernst theorem, Nernst statement, the third law of thermodynamics