大学物理 ›› 2014, Vol. 33 ›› Issue (12): 32-32.

• 著者文摘 • 上一篇    下一篇

空气中带电微粒的成核机理

曹万强 管焱俊   

  1. 有机化工新材料湖北省协同创新中心;湖北大学材料科学与工程学院,湖北武汉430062
  • 出版日期:2014-12-25 发布日期:2014-12-20

Nucleation mechanisms of charged micro-granules in the air

  • Online:2014-12-25 Published:2014-12-20

摘要: 大气中臭气层的减薄与雾霾的形成密切相关:紫外线照射下,煤燃烧和汽车排出的SO2和CO发生两次连续反应:CO和O2反应生成臭氧,臭氧与SO2和H2O反应生成H2SO4!H2O气溶胶分子;气溶胶分子受周围极性小分子的屏蔽形成了等离子屏蔽势,当极性小分子在两个气溶胶微粒间的等效诱导电荷量达到气溶胶所带电荷量的1/4时,气溶胶微粒将发生聚集.空气中极性小分子的电荷量增大或浓度增大时会导致气溶胶微粒间的吸引力增强,颗粒增大.气溶胶吸附微小固体颗粒形成了雾霾.

关键词: 带电微粒, 成核机理, 气溶胶

Abstract: The aspects of nucleation and growth mechanisms of charged aerosol particles in the air are dis- cussed. Due to the thinning ozone layer in the atmosphere, the extent of high-energy radiation to the earth surface increases, which causes two reactions when the high-energy radiation exposure to coal combustion and car discharges including SO2 and CO: CO and O2 reaction to generate ozone, and ozone reacts with SO2 and H2O to generate H2SO4 . H2O aerosols; hydrogen bonding with the aqueous aerosol surface condensation of tiny solid particles. In addition, based on the mechanism of polaron in condensed matter theory, the particles of two mutually exclusive with the same charge in the surrounding medium can produce attraction under the action of gathering and cohesion. Shielding potential model is used to derive conclusion that when the induced charge of polar small molecules between two aerosol particles by aerosol charges reaches a quarter of charge of an aerosol charge, two aerosol particles will attractive each other to merge a big one. The increase of charge quantity and density of polar small molecules in the air will lead to enhance attraction between the aerosol particles and degree of haze.

Key words: charged micro-granule, nucleation mechanism, aerosol

中图分类号: 

  • O552.4