教学研究

热容量随温度趋于零时为零不能作为热力学第三定律的一个表述

展开
  • 湖南大学物理与微电子科学学院理论物理研究所,湖南 长沙410082 
刘全慧(1963—),男,湖南华容人,湖南大学物理与微电子学院教授,博士生导师,主要从事大学物理教学研究工作.
刘全慧,E-mail: qhliu@hnu.edu.cn

收稿日期: 2025-07-10

  修回日期: 2025-12-15

  网络出版日期: 2026-08-06

基金资助

湖南省重点教改基金(HNJG20230147)资助

The fact that heat capacity is zero as temperature approaches zero cannot be used as a statement of the third law of thermodynamics

Expand
  • School for Theoretical Physics of College of Physics and Electronics, Hunan University, Changsha, Hunan 410082, China

Received date: 2025-07-10

  Revised date: 2025-12-15

  Online published: 2026-08-06

摘要

2006年,朱如曾在本刊上发表文章认为 “从能斯特定理导不出绝对零度下热容量的零极限”;2024年,本刊上发表文章(2024, 43(6):3)反对这一结论,认为“能斯特定理和绝对零度时的热容量表述是等价的”.本文论证为什么朱如曾的文章是正确的,讨论了为什么热容量随温度趋于零时为零不能作为热力学第三定律的一个表述. 


本文引用格式

刘全慧 . 热容量随温度趋于零时为零不能作为热力学第三定律的一个表述[J]. 大学物理, 2026 , 45(5) : 1 . DOI: 10.16854/j.cnki.1000-0712.250354

Abstract

In 2006, Zhu Ru-zeng published an article in this journal arguing that the zero limit of heat capacity at absolute zero cannot be derived from Nernst’s theorem; in 2024, an article published in this journal (2024, 43(6):3) opposed this conclusion, claiming that the Nernst’s theorem and the statement of vanishing of heat capacity at absolute zero are equivalent. This article demonstrates why Zhu Ru-zeng’s article is correct, and further discusses why the fact that heat capacity is zero as the temperature approaches zero cannot be used as a statement of the third law of thermodynamics.



文章导航

/