大学物理 ›› 2026, Vol. 45 ›› Issue (3): 35-.doi: 10.16854/j.cnki.1000-0712.250301

• 教学讨论 • 上一篇    下一篇

热容量表述与能斯特表述等效的严格证明

周颖慧,苏山河,赵英汝,陈金灿   

  1. 厦门大学 物理学系,福建 厦门361005
  • 收稿日期:2025-06-04 修回日期:2025-09-05 出版日期:2026-05-15 发布日期:2026-06-04
  • 作者简介:周颖慧(1982—),女,福建泉州人,厦门大学物理学系教授,博士,从事热力学统计物理相关的教学科研工作.
  • 基金资助:
    福建省高校物理学学科联盟教育教学改革研究项目(FJPHYS-2023)资助

Strict proof on the equivalence of the heat capacity statement and the #br# Nernst statement#br#

ZHOU Yinghui, SU Shanhe, ZHAO Yingru, CHEN Jincan   

  1. Department of Physics, Xiamen University, Xiamen, Fujian 361005, China
  • Received:2025-06-04 Revised:2025-09-05 Online:2026-05-15 Published:2026-06-04

摘要: 本文采用几种不同的方法严格地证明热容量表述与能斯特表述是可相互推导的、是等效的. 应用这两种表述取代一百多年来出现在教科书中的能斯特定理和/或绝对零度不能达到原理,成为热力学第三定律的创新表述,可确保热力学第三定律是客观世界的真实反映,从而完善经典热力学理论体系.

关键词: 热容量表述, 能斯特公式, 能斯特表述, 能斯特定理, 热力学第三定律

Abstract: Several different methods are used to prove strictly that the heat capacity statement and the Nernst statement are mutually derivable and equivalent. The application of the two statements to replace the Nernst theorem and/or the unattainability principle of absolute zero temperature, which have appeared in textbooks for more than one hundred years, as the innovative statements of the third law of thermodynamics can ensure that the third law of thermodynamics is a true reflection of the objective world, thus improving the theoretical system of classical thermodynamics. 


Key words: heat capacity statement, Nernst equation, Nernst statement, Nernst theorem, third law of thermodynamics